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Openai/6946f4fa-e8bc-800b-b77e-c62f6390a97c
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=== (Molecular Orbital Theory) === ==== ## ==== ===== : ===== ===== : ===== ===== a. 0 ===== b. 0.5 c. 1 d. 1.5 e. 2 ==== | | | | ==== | --- | --- | --- | | | | | | | | | | | | | ==== ### ==== Bond order=Nbonding−Nantibonding2\text{Bond order} = \frac{N_\text{bonding} - N_\text{antibonding}}{2}Bond order=2Nbonding−Nantibonding ===== - 每個 He 原子:2 電子 ===== * He₂:4 電子 * He₂⁺:少 1 電子 → 3 電子 ===== 對 He₂ 類型(只考慮 1s 軌域): ===== | | | | --- | --- | | | | | | | ===== BO=2−12=0.5\text{BO} = \frac{2 - 1}{2} = \boxed{0.5}BO=22−1=0.5 ===== ==== ### ==== ==== ## ==== ===== : ===== ===== : ===== ===== I. Be₂ is more stable because it contains both bonding and antibonding valence electrons. ===== II. H₂ has a higher bond order than Be₂. III. H₂ is more stable because it only contains σ1s electrons. IV. H₂ is more stable because it is diamagnetic, whereas Be₂ is paramagnetic. ===== a. I, II ===== b. III only c. II, III d. II, III, IV e. III, IV ==== | | | ==== | --- | --- | | | | | | | | | | ==== ### ==== ====== - 電子數:2 ====== * 填入:σ1s² * 鍵階: (2−0)/2=1(2 - 0)/2 = 1(2−0)/2=1 * 穩定、抗磁性 ====== - 每個 Be:2s² → 總 4 電子 ====== '' 填入: - σ2s² - σ''2s² * 鍵階: (2−2)/2=0(2 - 2)/2 = 0(2−2)/2=0 * 幾乎不穩定(實際上幾乎不存在) ===== #### ===== : ❌ 錯 反鍵電子會降低穩定性 ====== : ====== ✔ 正確(1 > 0) ====== : ====== ✔ 正確 ====== : ====== ❌ 錯 '' Be₂:σ2s² σ''2s² → 抗磁性 * 不是順磁性 ===== II, III\boxed{\text{II, III}}II, III ===== ==== ### ====
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