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Openai/6946f4fa-e8bc-800b-b77e-c62f6390a97c
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=== ## === ===== EN ===== Which of the following has the greatest bond strength? 中 下列哪一個物種具有最大的鍵強度? a. B₂ b. O₂⁻ c. CN⁻ d. O₂⁺ e. NO⁻ ===== : ===== ===== 依 MO 理論計算各物種鍵階: ===== | | | | --- | --- | | | | | | | | | | | | | | | | 鍵階最大者 → 鍵最強。 ===== ✅ c. CN⁻ ===== ==== ### ==== EN Consider the molecular orbital energy level diagrams for O₂ and NO. Which of the following statements is (are) correct? 中 考慮 O₂ 與 NO 的分子軌域能階圖,下列哪些敘述正確? I. Both molecules are paramagnetic. II. O₂ has a stronger bond than NO. III. NO is a homonuclear diatomic molecule. IV. The ionization energy of NO is less than that of NO⁺. ===== - I ✔ O₂(2 個未成對電子)、NO(1 個)→ 皆順磁 ===== * II ✘ NO 鍵階 2.5 > O₂ 鍵階 2 * III ✘ NO 為異核分子 * IV ✔ NO⁺ 更難再失電子 → IE 較大 ===== ✅ c. I and IV ===== ==== ### ==== EN How many σ bonds are present in the molecule shown? 中 圖示分子中共有幾個 σ 鍵? ===== 判斷原則: ===== * 單鍵 = 1 σ * 雙鍵 = 1 σ + 1 π * 三鍵 = 1 σ + 2 π 逐鍵計算所有鍵中的 σ 部分。 ===== ✅ c ===== ==== ### ==== EN How many lone pairs of electrons are present in the molecule shown? 中 該分子中共有幾對孤電子對? ===== 步驟: ===== # 找出各原子的價電子數 # 扣除成鍵電子 # 剩下即為孤對 ===== ✅ b ===== ==== ### ==== EN How many atoms in the molecule are sp hybridized? 中 該分子中有幾個原子為 sp 混成? ===== - sp 混成: - 2 電子域 - 線形 - 常見於三鍵或兩個雙鍵 ===== ===== 找出: ===== * C≡C * C≡N * 或 O=C=O 型結構 ===== ✅ a ===== ==== ### ==== EN Which of the following statements is (are) incorrect? 中 下列哪些敘述是錯誤的? (BF₃、XeF₄、N₂、HCN) ===== 逐條判斷: ===== * BF₃:sp² ✔ * XeF₄:非極性 ✔ * N₂:鍵階 3 ✔ * HCN:2 σ + 2 π ✔ ===== ✅ a. All four statements are correct ===== ==== ### ==== EN Which molecule contains the shortest carbon–carbon bond? 中 哪一個分子具有最短的 C–C 鍵? a. C₂H₂ b. C₂H₄ c. C₂H₆ d. C₂Cl₄ e. b and d ===== - C≡C(三鍵)最短 ===== * 僅 C₂H₂ 為三鍵 ===== ✅ a. C₂H₂ ===== ==== ### ==== EN What is the bond order of He₂⁺? 中 He₂⁺ 的鍵階為多少? ===== - He₂⁺:3 電子 ===== '' σ1s²、σ''1s¹ BO=2−12=0.5\text{BO} = \frac{2 - 1}{2} = 0.5BO=22−1=0.5 ===== ✅ b. 0.5 ===== ==== ### ==== EN When comparing Be₂ and H₂, which statements are correct? 中 比較 Be₂ 與 H₂,下列哪些敘述正確? ===== - H₂:鍵階 = 1,穩定 ===== * Be₂:鍵階 = 0,不穩定 正確敘述為: * II(H₂ 鍵階較高) * III(H₂ 較穩定) ===== ✅ c. II and III ===== ==== ### ==== EN Order the following from shortest to longest bond: C₂, B₂, H₂, N₂ 中 請將下列分子依鍵長由短到長排列。 ===== 鍵階比較: ===== | | | | --- | --- | | | | | | | | | | | | | ===== ✅ b. N₂ < C₂ < B₂ < H₂ =====
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